Please use this identifier to cite or link to this item: http://ena.lp.edu.ua:8080/handle/ntb/56095
Title: Synthesis of peroxid-containing hetero-chain amphiphilic oligomers and their colloid-chemical properties
Other Titles: Синтез пероксидо-вмісних гетероланцюгових амфіфільних олігомерів та їх колоїдно-хімічні властивості
Authors: Кузнецова, К. І.
Флейчук, Р. І.
Толстенко, А. Д.
Гевусь, О. І.
Kuznetsova, K.
Fleychuk, R.
Tolstenko, A.
Hevus, O.
Affiliation: Національний університет “Львівська політехніка”
Lviv Polytechnic National University
Bibliographic description (Ukraine): Synthesis of peroxid-containing hetero-chain amphiphilic oligomers and their colloid-chemical properties / K. Kuznetsova, R. Fleychuk, A. Tolstenko, O. Hevus // Chemistry, Technology and Application of Substances. — Lviv : Lviv Politechnic Publishing House, 2020. — Том 3. — № 1. — С. 27–32.
Bibliographic description (International): Synthesis of peroxid-containing hetero-chain amphiphilic oligomers and their colloid-chemical properties / K. Kuznetsova, R. Fleychuk, A. Tolstenko, O. Hevus // Chemistry, Technology and Application of Substances. — Lviv : Lviv Politechnic Publishing House, 2020. — Vol 3. — No 1. — P. 27–32.
Is part of: Chemistry, Technology and Application of Substances, 1 (3), 2020
Issue: 1
Issue Date: 24-Feb-2020
Publisher: Lviv Politechnic Publishing House
Place of the edition/event: Lviv
Lviv
DOI: doi.org/10.23939/ctas2020.01.027
Keywords: пероксидовмісні амфіфільні олігомери
поліетиленгліколі
оксетани
дикарбонові кислоти
peroxide-containing amphiphilic oligomers
polyethylene glycols
oxetanes
dicarboxylic acids
Number of pages: 6
Page range: 27-32
Start page: 27
End page: 32
Abstract: Синтезовано нові поверхнево-активні олігомери з альтернатним розміщенням гідрофільних та ліпофільних блоків на основі заміщених пероксидовмісних оксетанів та поліестерів вищих дикарбонових кислот і поліетиленгліколів різної молекулярної маси. Ацилюванням пероксидовмісного оксетану дихлорангідридами декан- та додекандіової кислот синтезовано відповідні біс(пероксиалкілоксетан)естери. Взаємодією отриманих діестерів із поліетиленгліколями PEG-300 та PEG-600 синтезовано амфіфільні олігомери, з реакційноздатними пероксидними групами в бічних відгалуженнях макроланцюга.
New surface-active oligomers were synthesized with the alternative placement of hydrophilic and lipophilic blocks based on substituted peroxide-containing oxetanes and polyesters of higher dicarboxylic acids and polyethylene glycols of different molecular weights. By acylation of peroxide-containing oxetane with dichloroanhydride decane and dodecanedioic acids, the corresponding bis (peroxyalkyloxetane) esters were synthesized. The interaction of the obtained diesters with polyethylene glycols PEG-300 and PEG-600 led to synthesys of amphiphilic oligomers, with reactive peroxide groups in the lateral branches of the macro-chain.
URI: http://ena.lp.edu.ua:8080/handle/ntb/56095
Copyright owner: © Національний університет “Львівська політехніка”, 2020
URL for reference material: http://dx.doi.org/10.32434/0321-40952019-123-2-5-11
References (Ukraine): 1. Gesang, T., Höper, R., Possart, W., Petermann, J., Hennemann, O.-D. (1996). AFM studies of the initial stages of spin-coated prepolymer film growth on silicon wafers. Advanced Materials, 8(10), 829–833. doi:10.1002/adma.19960081014.
2. Luo, Q., Chen, X., Liu, Z., Sun, Z., Ming, N. (1997). Deposition of oriented polymer films for liquid crystal slignment by pulsed laser ablation. Applied Surface Science, 108(1), 89–93. doi:10.1016/s0169-4332(96)00545-4.
3. Park, M., Harrison, C., Chaikin P.M., (1997) Block copolymer lithography: Periodic arrays of ~10 to the 11th power holes in 1 square centimeter. Science. 276 (5317). 1401–1404.
4. Schmolka, I. R. (1977). A review of block polymer surfactants. Journal of the American Oil Chemists’ Society. 54. 110.
5. Alexandridis, P., Hatton, T. A (1995). Poly(ethylene oxide)-poly(propylene oxide)-poly (ethylene oxide) block copolymer surfactants in aqueous solutions and at interfaces: thermodynamics, structure, dynamics, and modeling. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 96(1–2), 1–46. doi:10.1016/0927-7757(94)03028-x.
6. Voronov A., Vasylyev S., Kohut A., Peukert, W. (2008). Surface activity of new invertible amphiphilic polyesters based on poly(ethylene glycol) and aliphatic dicarboxylic acids. Journal of Colloid and Interface Science, 323(2), 379–385. doi:10.1016/j.jcis.2008.04.053.
7. Voronov, A., Kohut, A., Peukert, W., Voronov, S., Gevus, O., Tokarev, V. (2006). Invertible Architectures from Amphiphilic Polyesters. Langmuir, 22(5), 1946–1948. doi:10.1021/la052225z.
8. Bahatofunktsionalni nanomaterialy dlia biolohii i medytsyny: molekuliarnyi dyzain, syntez i zastosuvannia (za redaktsiyeyu ch.-korespondenta NAN Ukrainy R. S. Stoika). [Multifunctional nanomaterials for biology and medicine: molecular design, synthesis and application]. (Edited by R. S. Stoika, corresponding Member of NAS of Ukraine), Kyiv, Naukova dumka. 2017. 363 p. (in Ukrainian).
9. Nishikubo, T., Kameyama, A., Kudo, H. (2006). Synthesis of Polymers with Well-defined Structures by Novel Ring-opening Reactions of Oxetanes. Journal of Synthetic Organic Chemistry, Japan, 64(9), 934–946. doi:10.5059/yukigoseikyokaishi.64.934.
10. Kudo, H., Nishikubo, T. (2007). Catalytic reactions of oxetanes with protonic reagents and aprotic reagents leading to novel polymers. Journal of Polymer Science Part A: Polymer Chemistry, 45(5), 709–726. doi:10.1002/pola.21828.
11. Semlitsch, S., Torron, S., Johansson, M., Martinelle, M. (2016). Enzymatic catalysis as a versatile tool for the synthesis of multifunctional, bio-based oligoester resins. Green Chemistry, 18(7), 1923–1929. doi:10.1039/c5gc02597d.
12. Kuznetsova К. І., Vostres V. B., Fleychuk R. I., Hevus O. I., “Synthesis of surface-active monomers and peroxides on a disubstituted oxetane basis”. Voprosy khimii i khimicheskoi tekhnologii, 2019, No. 2, pp. 5–11. http://dx.doi.org/10.32434/0321-40952019-123-2-5-11
13. Nishikubo, T., & Kudo, H. (2007). High Performance Photo-curable Polymers and Oligomers Based on Novel Ring-opening Reactions of Oxetanes. MRS Proceedings, 1005. doi:10.1557/proc-1005-q02-04.
14. Bobrova K. I., Fleychuk R. I., Hevus O. I. “SyntezneyonohennykhPARnaosnovidyzamishchenykhok setaniv”. Visnyk Natsional’noho universytetu “L’vivs’ka politekhnika” Khimiya, tekhnolohiya rechovyn ta yikh zastosuvannya, 2017, No. 868, P. 3–8.
15. Bobrova K. I., Fleychuk R. I., Hevus O. I. Decomposition of three-, four-, and five-membered oxygenheterocyclesbytert-butylhydroperoxide // Bulletin of the Lviv Polytechnic National University. No. 886. 2018. С. 52–58.
16. Toroptseva A. M., Belogorodskaya K. V., Bondarenko V. M. Laboratornyy praktikum po khimii i tekhnologii vysokomolekulyarnykh soyedineniy. L.: Khimiya, 1972. 416 p.
References (International): 1. Gesang, T., Höper, R., Possart, W., Petermann, J., Hennemann, O.-D. (1996). AFM studies of the initial stages of spin-coated prepolymer film growth on silicon wafers. Advanced Materials, 8(10), 829–833. doi:10.1002/adma.19960081014.
2. Luo, Q., Chen, X., Liu, Z., Sun, Z., Ming, N. (1997). Deposition of oriented polymer films for liquid crystal slignment by pulsed laser ablation. Applied Surface Science, 108(1), 89–93. doi:10.1016/s0169-4332(96)00545-4.
3. Park, M., Harrison, C., Chaikin P.M., (1997) Block copolymer lithography: Periodic arrays of ~10 to the 11th power holes in 1 square centimeter. Science. 276 (5317). 1401–1404.
4. Schmolka, I. R. (1977). A review of block polymer surfactants. Journal of the American Oil Chemists’ Society. 54. 110.
5. Alexandridis, P., Hatton, T. A (1995). Poly(ethylene oxide)-poly(propylene oxide)-poly (ethylene oxide) block copolymer surfactants in aqueous solutions and at interfaces: thermodynamics, structure, dynamics, and modeling. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 96(1–2), 1–46. doi:10.1016/0927-7757(94)03028-x.
6. Voronov A., Vasylyev S., Kohut A., Peukert, W. (2008). Surface activity of new invertible amphiphilic polyesters based on poly(ethylene glycol) and aliphatic dicarboxylic acids. Journal of Colloid and Interface Science, 323(2), 379–385. doi:10.1016/j.jcis.2008.04.053.
7. Voronov, A., Kohut, A., Peukert, W., Voronov, S., Gevus, O., Tokarev, V. (2006). Invertible Architectures from Amphiphilic Polyesters. Langmuir, 22(5), 1946–1948. doi:10.1021/la052225z.
8. Bahatofunktsionalni nanomaterialy dlia biolohii i medytsyny: molekuliarnyi dyzain, syntez i zastosuvannia (za redaktsiyeyu ch.-korespondenta NAN Ukrainy R. S. Stoika). [Multifunctional nanomaterials for biology and medicine: molecular design, synthesis and application]. (Edited by R. S. Stoika, corresponding Member of NAS of Ukraine), Kyiv, Naukova dumka. 2017. 363 p. (in Ukrainian).
9. Nishikubo, T., Kameyama, A., Kudo, H. (2006). Synthesis of Polymers with Well-defined Structures by Novel Ring-opening Reactions of Oxetanes. Journal of Synthetic Organic Chemistry, Japan, 64(9), 934–946. doi:10.5059/yukigoseikyokaishi.64.934.
10. Kudo, H., Nishikubo, T. (2007). Catalytic reactions of oxetanes with protonic reagents and aprotic reagents leading to novel polymers. Journal of Polymer Science Part A: Polymer Chemistry, 45(5), 709–726. doi:10.1002/pola.21828.
11. Semlitsch, S., Torron, S., Johansson, M., Martinelle, M. (2016). Enzymatic catalysis as a versatile tool for the synthesis of multifunctional, bio-based oligoester resins. Green Chemistry, 18(7), 1923–1929. doi:10.1039/P.5gc02597d.
12. Kuznetsova K. I., Vostres V. B., Fleychuk R. I., Hevus O. I., "Synthesis of surface-active monomers and peroxides on a disubstituted oxetane basis". Voprosy khimii i khimicheskoi tekhnologii, 2019, No. 2, pp. 5–11. http://dx.doi.org/10.32434/0321-40952019-123-2-5-11
13. Nishikubo, T., & Kudo, H. (2007). High Performance Photo-curable Polymers and Oligomers Based on Novel Ring-opening Reactions of Oxetanes. MRS Proceedings, 1005. doi:10.1557/proc-1005-q02-04.
14. Bobrova K. I., Fleychuk R. I., Hevus O. I. "SyntezneyonohennykhPARnaosnovidyzamishchenykhok setaniv". Visnyk Natsional’noho universytetu "L’vivs’ka politekhnika" Khimiya, tekhnolohiya rechovyn ta yikh zastosuvannya, 2017, No. 868, P. 3–8.
15. Bobrova K. I., Fleychuk R. I., Hevus O. I. Decomposition of three-, four-, and five-membered oxygenheterocyclesbytert-butylhydroperoxide, Bulletin of the Lviv Polytechnic National University. No. 886. 2018. P. 52–58.
16. Toroptseva A. M., Belogorodskaya K. V., Bondarenko V. M. Laboratornyy praktikum po khimii i tekhnologii vysokomolekulyarnykh soyedineniy. L., Khimiya, 1972. 416 p.
Content type: Article
Appears in Collections:Chemistry, Technology and Application of Substances. – 2020. – Vol. 3, No. 1



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