Please use this identifier to cite or link to this item: http://ena.lp.edu.ua:8080/handle/ntb/56094
Title: Фізико-хімічні дослідження структури гумінових кислот
Other Titles: Physical and chemical researches on the structure of humic acids
Authors: Кочубей, В. В.
Семенюк, І. В.
Карпенко, О. В.
Скорохода, В. Й.
Kochubei, V.
Semeniuk, I.
Karpenko, O.
Skorokhoda, V.
Affiliation: Національний університет “Львівська політехніка”
Відділення фізико-хімії горючих копалин ІнФОВ ім. Л. М. Литвиненка НАН України
Lviv Polytechnic National University
Department of Physical Chemistry of Fossil Fuels In POCCC, National Academy of Sciences of Ukraine
Bibliographic description (Ukraine): Фізико-хімічні дослідження структури гумінових кислот / В. В. Кочубей, І. В. Семенюк, О. В. Карпенко, В. Й. Скорохода // Chemistry, Technology and Application of Substances. — Lviv : Lviv Politechnic Publishing House, 2020. — Том 3. — № 1. — С. 22–26.
Bibliographic description (International): Physical and chemical researches on the structure of humic acids / V. Kochubei, I. Semeniuk, O. Karpenko, V. Skorokhoda // Chemistry, Technology and Application of Substances. — Lviv : Lviv Politechnic Publishing House, 2020. — Vol 3. — No 1. — P. 22–26.
Is part of: Chemistry, Technology and Application of Substances, 1 (3), 2020
Issue: 1
Issue Date: 24-Feb-2020
Publisher: Lviv Politechnic Publishing House
Place of the edition/event: Lviv
Lviv
DOI: doi.org/10.23939/ctas2020.01.022
Keywords: гумінові кислоти
біополімери
термічний аналіз
УФ/Віз-спектроскопія
humic acids
biopolymers
thermal analysis
UV/Vis spectroscopy
Number of pages: 5
Page range: 22-26
Start page: 22
End page: 26
Abstract: На основі комплексного термічного, титриметричного та УФ/Віз-спектрального аналізів досліджено структуру та визначено вміст функціональних груп у молекулах гумінових кислот, одержаних із різної сировини – копроліту, торфу та леонардиту. Термічну стійкість речовин досліджено в повітряному середовищі в інтервалі температур 20–1000 °С. Виявлено, що в гумінових кислотах, одержаних із різної сировини, вміст аліфатичної складової є переважаючим. Зразок гумінової кислоти, отриманий із копроліту, відзначається найбільшим вмістом аліфатичних фрагментів та підвищеним вмістом кислотних груп.
Based on the complex thermal, titrimetric and UV/Vis spectral analyzes, the structure and the content of functional groups in the molecules of humic acids obtained from different raw materials – coprolite, peat and leonardite – were investigated. The thermal stability of the substances was investigated in the air in the temperature range 20–1000 °C. It has been found that the content of the aliphatic component is predominant in humic acids obtained from different raw materials. A sample of humic acid obtained from coprolite has the highest content of aliphatic fragments and increased content of acid groups.
URI: http://ena.lp.edu.ua:8080/handle/ntb/56094
Copyright owner: © Національний університет “Львівська політехніка”, 2020
References (Ukraine): 1. Romenskyi V. Yu. (2011). Vplyv zroshennia I mineralnoho udobrennia na riven rodiuchosti gruntu pryvyroshchuvanipolovykh kultur v umovakh pivdennoho Stepu Ukrainy. Biul. In-tu silsk. hosp-va stepovoi zony, 1, 140–144 (in Ukrainian).
2. Piccolo A. (2002). The Supramolecular structure of humic substances. A novel understanding of humus chemistry and implications in soil science. Advances in Agronomy, 75, 57–134.
3. Horovaia A. Y., Orlov D. S., Shcherbenko O. V. (1995). Humynovue veshchestva. Stroenye, funktsyy, mekhanizm deistvyia, protektorne svoistva, ekolohycheskaia rol. Kyev: Naukova Dumka (in Ukrainian).
4. Bozkurt S., Lucisano M., Moreno L., Neretnieks I. (2001). Peat as a potential analogue for the long-term evolution in landfills. Earth-ScienceReviews, 53, 95–147.
5. Tytov Y. N. (2009). Patent RF. 2009126851. Moskva: Reestr patentov na yzobretenyia Rossyiskoi Federatsyy [in Russian].
6. Luchnyk N. A., Ivanov A. E., Merkulov A. I. (1997). Humaty natriiu na posivakh zernovykh kultur. Khymyia v selskom khoziaistve, 2, 28–30 (inUkrainian).
7. Butaev B. S., Zoltoev E. V., Bodoev N. V., Bukov Y. P., Dashytsurenova A.D. Otsenka fyzyolohycheskoi aktyvnosty humynovukh veshchestv okyslennukh uhlei. Khymyia v ynteresakh ustoichyvoho razvytyia, 13(4), 501–50 [in Russian].
8. Harmash S. M. (2009). Vplyv naturalnoho stymuliatora roslyn biohumatu na vrozhainist ovochevykh kultur. Visnyk Dnipropetrovskoho derzhavnoho ahrarnoho universytetu, 1, 47–50 (in Ukrainian).
9. Chukhareva N. V., Shyshmyna L. V., Novykov A. A. (2003). Vlyianye termoobrabotky torfa na sostav y svoistva humynovukh kyslot. Khymyia tverdoho toplyva, 4, 38–44 [in Russian].
10. Helen Lavrenyuk, Victoria Kochubei, Oleg Mykhalichko, Borys Mykhalichko (2018). Metal – coor dinated epoxy polymers with suppressed combustibility. Preparation technology, thermal degradation, and combustibility test of new epoxy – amine polymers containing the curing agent with chelated copper(II) carbonate. Fire and Materials, 42(3), 266–277.
11. Eshwar M., Srilatha M., Bhanu Rekha K., Harish Kumar Sharma S. (2017). Characterization of Humic Substances by Functional Groups and Spectroscopic Methods. International Jornal Current Microbiology Applied Sciences, 6(10), 1768–1774.
12. Souza F., Bragança S. R. (2018) Extraction and characterization of humic acid from coal for the application as dispersant of ceramic powders. Journal of Materials Research and Technology, 7(3), 254–260.
13. Haddad G., Ali F. E., Mouneimne A. H. (2015). Humicmatterofcompost: determination of humic spectroscopic ratio (E4/E6). Current Science International, 4(1), 56–72.
14. Permynova Y. V. (2020). Analyz, klassyfykatsyiayprohnozsvoistvhumynovukhkyslot [Analysis, classification and prediction of humic acid properties] (Doctor’s thesis). Moskva [in Russian].
References (International): 1. Romenskyi V. Yu. (2011). Vplyv zroshennia I mineralnoho udobrennia na riven rodiuchosti gruntu pryvyroshchuvanipolovykh kultur v umovakh pivdennoho Stepu Ukrainy. Biul. In-tu silsk. hosp-va stepovoi zony, 1, 140–144 (in Ukrainian).
2. Piccolo A. (2002). The Supramolecular structure of humic substances. A novel understanding of humus chemistry and implications in soil science. Advances in Agronomy, 75, 57–134.
3. Horovaia A. Y., Orlov D. S., Shcherbenko O. V. (1995). Humynovue veshchestva. Stroenye, funktsyy, mekhanizm deistvyia, protektorne svoistva, ekolohycheskaia rol. Kyev: Naukova Dumka (in Ukrainian).
4. Bozkurt S., Lucisano M., Moreno L., Neretnieks I. (2001). Peat as a potential analogue for the long-term evolution in landfills. Earth-ScienceReviews, 53, 95–147.
5. Tytov Y. N. (2009). Patent RF. 2009126851. Moskva: Reestr patentov na yzobretenyia Rossyiskoi Federatsyy [in Russian].
6. Luchnyk N. A., Ivanov A. E., Merkulov A. I. (1997). Humaty natriiu na posivakh zernovykh kultur. Khymyia v selskom khoziaistve, 2, 28–30 (inUkrainian).
7. Butaev B. S., Zoltoev E. V., Bodoev N. V., Bukov Y. P., Dashytsurenova A.D. Otsenka fyzyolohycheskoi aktyvnosty humynovukh veshchestv okyslennukh uhlei. Khymyia v ynteresakh ustoichyvoho razvytyia, 13(4), 501–50 [in Russian].
8. Harmash S. M. (2009). Vplyv naturalnoho stymuliatora roslyn biohumatu na vrozhainist ovochevykh kultur. Visnyk Dnipropetrovskoho derzhavnoho ahrarnoho universytetu, 1, 47–50 (in Ukrainian).
9. Chukhareva N. V., Shyshmyna L. V., Novykov A. A. (2003). Vlyianye termoobrabotky torfa na sostav y svoistva humynovukh kyslot. Khymyia tverdoho toplyva, 4, 38–44 [in Russian].
10. Helen Lavrenyuk, Victoria Kochubei, Oleg Mykhalichko, Borys Mykhalichko (2018). Metal – coor dinated epoxy polymers with suppressed combustibility. Preparation technology, thermal degradation, and combustibility test of new epoxy – amine polymers containing the curing agent with chelated copper(II) carbonate. Fire and Materials, 42(3), 266–277.
11. Eshwar M., Srilatha M., Bhanu Rekha K., Harish Kumar Sharma S. (2017). Characterization of Humic Substances by Functional Groups and Spectroscopic Methods. International Jornal Current Microbiology Applied Sciences, 6(10), 1768–1774.
12. Souza F., Bragança S. R. (2018) Extraction and characterization of humic acid from coal for the application as dispersant of ceramic powders. Journal of Materials Research and Technology, 7(3), 254–260.
13. Haddad G., Ali F. E., Mouneimne A. H. (2015). Humicmatterofcompost: determination of humic spectroscopic ratio (E4/E6). Current Science International, 4(1), 56–72.
14. Permynova Y. V. (2020). Analyz, klassyfykatsyiayprohnozsvoistvhumynovukhkyslot [Analysis, classification and prediction of humic acid properties] (Doctor’s thesis). Moskva [in Russian].
Content type: Article
Appears in Collections:Chemistry, Technology and Application of Substances. – 2020. – Vol. 3, No. 1



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