Please use this identifier to cite or link to this item: http://ena.lp.edu.ua:8080/handle/ntb/56087
Title: Дослідження кінетики прищепленої полімеризації у тонкому шарі 2-гідроксіетилметакрилату з полівінілпіролідоном
Other Titles: Investigation of the kinetics of graft polymerization in a thin layer of 2-hydroxiethyl methacrylate with polyvinylpyrrolidone
Authors: Мельник, Ю. Я.
Кос, П. О.
Суберляк, О. В.
Melnyk, Yu.
Kos, P.
Suberlyak, O.
Affiliation: Національний університет “Львівська політехніка”
Lviv Polytechnic National University
Bibliographic description (Ukraine): Мельник Ю. Я. Дослідження кінетики прищепленої полімеризації у тонкому шарі 2-гідроксіетилметакрилату з полівінілпіролідоном / Ю. Я. Мельник, П. О. Кос, О. В. Суберляк // Chemistry, Technology and Application of Substances. — Lviv : Lviv Politechnic Publishing House, 2020. — Том 3. — № 1. — С. 209–213.
Bibliographic description (International): Melnyk Yu. Investigation of the kinetics of graft polymerization in a thin layer of 2-hydroxiethyl methacrylate with polyvinylpyrrolidone / Yu. Melnyk, P. Kos, O. Suberlyak // Chemistry, Technology and Application of Substances. — Lviv : Lviv Politechnic Publishing House, 2020. — Vol 3. — No 1. — P. 209–213.
Is part of: Chemistry, Technology and Application of Substances, 1 (3), 2020
Issue: 1
Issue Date: 24-Feb-2020
Publisher: Lviv Politechnic Publishing House
Place of the edition/event: Lviv
Lviv
DOI: doi.org/10.23939/ctas2020.01.209
Keywords: 2-гідроксіетилметакрилат
полівінілпіролідон
полімеризація
тонкий шар
кінетика
прищеплений кополімер
2-hydroxyethyl methacrylate
polyvinylpyrrolidone
polymerization
kinetics
thin layer
graft copolymer
Number of pages: 5
Page range: 209-213
Start page: 209
End page: 213
Abstract: Досліджено кінетику полімеризації 2-гідроксіетилметакрилату з полівінілпіролідоном у тонкому шарі. Побудовано екзотерми реакції (ко)полімеризації в масі. Визначено порядок реакції за ініціатором, мономером і полімером та виведено математичну залежність сумарної швидкості прищепленої кополімеризації ГЕМА до ПВП. Визначено залежність кількості ПВП, що бере участь у реакції прищепленої полімеризації від його концентрації в композиції, природи та концентрації ініціатора і температури процесу.
The kinetics of polymerization of 2-hydroxyethyl methacrylate with polyvinylpyrrolidone in a thin layer were studied. The dependences of the conversion for polymerization HEMA with PVP in mass and in solvent were determined. (Co)polymerization exotherms for the reaction in mass were calculated. The reaction order by initiator, monomer and polymer was determined and the mathematical dependence of the total rate of grafted copolymerization of HEMA to PVP was calculated. Amount of the reacted PVP in the graft polymerization reaction in dependence on concentration, nature and concentration of the initiator in the composition and temperature was determined.
URI: http://ena.lp.edu.ua:8080/handle/ntb/56087
Copyright owner: © Національний університет “Львівська політехніка”, 2020
URL for reference material: https://doi.org/10.1016/S0142-9612(01)00035-7
https://doi.org/10.23939/ctas2019.01.121
https://doi.org/10.1021/ac60081a031
https://doi.org/10.1002/apmc.1983.051180101
References (Ukraine): 1. Lavrov, N. A., &Kryzhanovskaya, T. S. (1995). Poliakrilaty v meditsine. Plasticheskiye massy, 2, 42–43.
2. Lavrov, N. A.,& Nikolayev, A. F. (1986). Oblasti primeneniya polimerov na osnove 2-gidroksietilmetakrilata. Plasticheskiye massy, 8, 55–57.
3. García-Millán, E., Koprivnik, S., &Otero-Espinar, F. J. (2015). Drug loading optimization and extended drug delivery of corticoids from pHEMA based soft contact lenses hydrogels via chemical and microstructural modifications. International Journal of Pharmaceutics, 487(1-2), 260-269. doi: 10.1016/j.ijpharm.2015.04.037
4. Hoch, G., Chauhan, A., & Radke, C. J. (2003). Permeability and diffusivity for water transport through hydrogel membranes. Journal of Membrane Science, 214(2), 199–209. doi: 10.1016/S0376-7388(02)00546-X
5. Dziubla, T. D., Torjman, M. C., Joseph, J. I., Murphy- Tatum, M., & Lowman, A. M. (2001). Evaluation of porous networks of poly(2-hydroxyethyl methacrylate) as interfacial drug delivery devices. Biomaterials, 22(21), 2893–2899. https://doi.org/10.1016/S0142-9612(01)00035-7
6. Saini, R. K., Bagri, L. P., & Bajpai, A. K. (2014). Poly(2-hydroxyethyl methacrylate) (PHEMA) based nanoparticles for drug delivery applications: A review. Nano Science and Nano Technology: An Indian Journal, 8(11), 416–427.
7. Skorokhoda, V., Melnyk, Y., Semenyuk, N, & Suberlyak, O. (2015). Obtaining peculiarities and properties of polyvinylpyrrolidone copolymers with hydrophobic vinyl monomers. Chemistry& Chemical Technology, 9(1), 55–59.
8. Skorokhoda, V. Y., Melnyk, Yu. Ya., Shalata, V. Ya., Skorokhoda, T. V., & Suberliak, S. A. (2017). An investigation of obtaining patterns, structure and diffusion properties of biomedical purpose hydrogel membranes. Eastern-European Journal of Enterprise Technologies.1, 6(85), 50-55. doi: 10.15587/1729-4061.2017.92368
9. Skorokhoda, V., Melnyk, Y., Semenyuk, N., Ortynska, N., & Suberlyak, O. (2017). Film hydrogels on the basis of polyvinylpyrrolidone copolymers with regulated sorption-desorption characteristics. Chemistry & Chemical Technolog, 11(2), 171–174. doi: 10.15587/1729-4061.2017.92368
10. Skorokhoda, V. Y., Semenyuk, N. B., Dzyaman, I. Z., Levyts’ka, KH. V., &Dudok H. D. (2018). Vplyv pryrody kal’tsiyevmisnoho napovnyuvacha na zakonomirnosti oderzhannya ta vlastyvosti osteoplastychnykh porystykh kompozytiv. Pytannya khimiyi i khimichnoyi tekhnolohiyi, 2(117), 101–108.
11. Skorokhoda, V. Y., Dudok, H. D., Dzyaman, I. Z., &Kysil’, KH. V. (2019). Intensyfikatsiya protsesu oderzhannya osteoplastychnykh porystykh kompozytiv z vykorystannyam ul’trazvuku. Khimiya, tekhnolohiya rechovyn ta yikh zastosuvannya, 2(1), 121–126. doi: https://doi.org/10.23939/ctas2019.01.121
12. Levy, G. B., Fergus, D. (1953). Microdetermination of polyvinylpyrrolidone in aqueous solution and in body fluids. Аnа1ytical Chemistry, 25(9), 1408–1410. https://doi.org/10.1021/ac60081a031
13. Baghdasaryan, X. S. (1966). The theory of radical polymerization. Moscow: Science.
14. Berlin, A. A., Vol’fson, S. A., & Yenikopyan, N. S. (1978). Kinetika polimerizatsionnykh protsessov. Moskva: Khimiya.
15. Staszewska, D. U. (1983). The oxidation of poly- (vinyl pyrrolidone) with Ce(IV). MacromolecularMaterials and Engineering, 118(1), 1-17. doi:https://doi.org/10.1002/apmc.1983.051180101
16. Suberlyak, O. V., Skorokhoda,V. I., &Tir, I. G. (1989). Vliyaniye kompleksoobrazovaniya na polimerizatsiyu 2-oksietilenmetakrilata v prisutstvii polivinilpirrolidona. Vysokomolekulyarnyye soyedineniya, 31(5B), 336–340.
References (International): 1. Lavrov, N. A., &Kryzhanovskaya, T. S. (1995). Poliakrilaty v meditsine. Plasticheskiye massy, 2, 42–43.
2. Lavrov, N. A.,& Nikolayev, A. F. (1986). Oblasti primeneniya polimerov na osnove 2-gidroksietilmetakrilata. Plasticheskiye massy, 8, 55–57.
3. García-Millán, E., Koprivnik, S., &Otero-Espinar, F. J. (2015). Drug loading optimization and extended drug delivery of corticoids from pHEMA based soft contact lenses hydrogels via chemical and microstructural modifications. International Journal of Pharmaceutics, 487(1-2), 260-269. doi: 10.1016/j.ijpharm.2015.04.037
4. Hoch, G., Chauhan, A., & Radke, C. J. (2003). Permeability and diffusivity for water transport through hydrogel membranes. Journal of Membrane Science, 214(2), 199–209. doi: 10.1016/S0376-7388(02)00546-X
5. Dziubla, T. D., Torjman, M. C., Joseph, J. I., Murphy- Tatum, M., & Lowman, A. M. (2001). Evaluation of porous networks of poly(2-hydroxyethyl methacrylate) as interfacial drug delivery devices. Biomaterials, 22(21), 2893–2899. https://doi.org/10.1016/S0142-9612(01)00035-7
6. Saini, R. K., Bagri, L. P., & Bajpai, A. K. (2014). Poly(2-hydroxyethyl methacrylate) (PHEMA) based nanoparticles for drug delivery applications: A review. Nano Science and Nano Technology: An Indian Journal, 8(11), 416–427.
7. Skorokhoda, V., Melnyk, Y., Semenyuk, N, & Suberlyak, O. (2015). Obtaining peculiarities and properties of polyvinylpyrrolidone copolymers with hydrophobic vinyl monomers. Chemistry& Chemical Technology, 9(1), 55–59.
8. Skorokhoda, V. Y., Melnyk, Yu. Ya., Shalata, V. Ya., Skorokhoda, T. V., & Suberliak, S. A. (2017). An investigation of obtaining patterns, structure and diffusion properties of biomedical purpose hydrogel membranes. Eastern-European Journal of Enterprise Technologies.1, 6(85), 50-55. doi: 10.15587/1729-4061.2017.92368
9. Skorokhoda, V., Melnyk, Y., Semenyuk, N., Ortynska, N., & Suberlyak, O. (2017). Film hydrogels on the basis of polyvinylpyrrolidone copolymers with regulated sorption-desorption characteristics. Chemistry & Chemical Technolog, 11(2), 171–174. doi: 10.15587/1729-4061.2017.92368
10. Skorokhoda, V. Y., Semenyuk, N. B., Dzyaman, I. Z., Levyts’ka, KH. V., &Dudok H. D. (2018). Vplyv pryrody kal’tsiyevmisnoho napovnyuvacha na zakonomirnosti oderzhannya ta vlastyvosti osteoplastychnykh porystykh kompozytiv. Pytannya khimiyi i khimichnoyi tekhnolohiyi, 2(117), 101–108.
11. Skorokhoda, V. Y., Dudok, H. D., Dzyaman, I. Z., &Kysil’, KH. V. (2019). Intensyfikatsiya protsesu oderzhannya osteoplastychnykh porystykh kompozytiv z vykorystannyam ul’trazvuku. Khimiya, tekhnolohiya rechovyn ta yikh zastosuvannya, 2(1), 121–126. doi: https://doi.org/10.23939/ctas2019.01.121
12. Levy, G. B., Fergus, D. (1953). Microdetermination of polyvinylpyrrolidone in aqueous solution and in body fluids. Ana1ytical Chemistry, 25(9), 1408–1410. https://doi.org/10.1021/ac60081a031
13. Baghdasaryan, X. S. (1966). The theory of radical polymerization. Moscow: Science.
14. Berlin, A. A., Vol’fson, S. A., & Yenikopyan, N. S. (1978). Kinetika polimerizatsionnykh protsessov. Moskva: Khimiya.
15. Staszewska, D. U. (1983). The oxidation of poly- (vinyl pyrrolidone) with Ce(IV). MacromolecularMaterials and Engineering, 118(1), 1-17. doi:https://doi.org/10.1002/apmc.1983.051180101
16. Suberlyak, O. V., Skorokhoda,V. I., &Tir, I. G. (1989). Vliyaniye kompleksoobrazovaniya na polimerizatsiyu 2-oksietilenmetakrilata v prisutstvii polivinilpirrolidona. Vysokomolekulyarnyye soyedineniya, 31(5B), 336–340.
Content type: Article
Appears in Collections:Chemistry, Technology and Application of Substances. – 2020. – Vol. 3, No. 1



Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.