Please use this identifier to cite or link to this item: http://ena.lp.edu.ua:8080/handle/ntb/55800
Title: Preparation and Characterization of Molecular Imprinted Polymer for the Selective Recognition of Serotonin
Other Titles: Одержання та характеристика полімерів з “молекулярними відтисками” для селективного розпізнавання серотоніну
Authors: Hepokur, Ceylan
Nursevin Öztop, H.
Saraydin, Dursun
Affiliation: Sivas Cumhuriyet University
Bibliographic description (Ukraine): Hepokur C. Preparation and Characterization of Molecular Imprinted Polymer for the Selective Recognition of Serotonin / Ceylan Hepokur, H. Nursevin Öztop, Dursun Saraydin // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2020. — Vol 14. — No 2. — P. 195–204.
Bibliographic description (International): Hepokur C. Preparation and Characterization of Molecular Imprinted Polymer for the Selective Recognition of Serotonin / Ceylan Hepokur, H. Nursevin Öztop, Dursun Saraydin // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2020. — Vol 14. — No 2. — P. 195–204.
Is part of: Chemistry & Chemical Technology, 2 (14), 2020
Issue: 2
Volume: 14
Issue Date: 24-Jan-2020
Publisher: Видавництво Львівської політехніки
Lviv Politechnic Publishing House
Place of the edition/event: Львів
Lviv
DOI: doi.org/10.23939/chcht14.02.195
Keywords: акриламід
метакрилова кислота
метакриламід
молекулярно-імпринтовані полімери
серотонін
acrylamide
methacrylic acid
methacrylamide
molecularly imprinted polymers
serotonin
Number of pages: 10
Page range: 195-204
Start page: 195
End page: 204
Abstract: Одержано полімери «з молекулярними відтисками» (молекулярно імпринтовані полімери, MIП) для високоселективного розпізнавання серотоніну. Як мономери для одержання МІП використано акриламід, метакрилову кислоту та метакриламид. Проведено полімеризацію функціональних мономерів з диметакрилатом етиленгліколю, діакрилатом 1,4- бутандіолу і триметилпропантриакрилатом з серотоніном. Видалення серотоніну з MIП проводили за допомогою суміші метанол/оцтова кислота (4:1). Синтезовано неімпринтовані полімери (НІП) без серотоніну. Одержані полімери досліджено за допомогою методів Фур‘є-спектроскопії, диференційно скануючої калориметрії, термогравіметричного аналізу та скануючої електронної мікроскопії. Встановлено вплив температури, pH і концентрації на адсорбцію серотоніну. Визначено значення селективності таможливість повторного використання.
Molecularly imprinted polymers (MIPs) were prepared for highly selective recognition of serotonin. Acrylamide, methacrylic acid and methacrylamide were selected as the monomers for the production of MIPs. Functional monomers were polymerized with ethylene glycol dimethacrylate, 1,4-butanediol diacrylate, and trimethylpropane triacrylate with serotonin (MIP-EGDMA, MIP-BUT and MIP-TMT). Serotonin was removed from MIP by the mixture of methanol/acetic acid (4:1). Nonimprinted polymers (NIPs) were synthesized without serotonin (NIP-EGDMA, NIP-BUT and NIP-TMT). For the characterization of synthesized polymers FTIR, DSC, TGA, and SEM analysis were investigated. The parameters that affect the adsorption of serotonin on polymers such as temperature, pH and concentration were evaluated. The selectivity and reusability studies were also investigated.
URI: http://ena.lp.edu.ua:8080/handle/ntb/55800
Copyright owner: © Національний університет “Львівська політехніка”, 2020
© Hepokur C., Oztop N., Saraydin D., 2020
URL for reference material: https://doi.org/10.1016/j.apsusc.2018.07.142
https://doi.org/10.1002/cbdv.200490069
https://doi.org/10.3390/ijms9122333
https://doi.org/10.1016/j.aca.2016.02.046
https://doi.org/10.3390/i7050155
https://doi.org/10.1016/j.bios.2017.08.022
https://doi.org/10.1016/j.aca.2005.01.052
https://doi.org/10.3176/proc.2018.2.04
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https://doi.org/10.1002/pola.20186
https://doi.org/10.1016/S0378-4347(99)00057-2
https://doi.org/10.1016/j.aca.2007.01.016
https://doi.org/10.1016/j.snb.2012.05.040
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https://doi.org/10.1016/j.chroma.2006.09.065
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[2] Mathews C., van Holde K., Biochemistry: The Benjamin/Cummings Publ. Co., Redwood City, California 1990.
[3] Sengupta B., Chaudhuri S., Banerjee A., Sengupta P., Chem. Biodivers., 2004, 1, 868. https://doi.org/10.1002/cbdv.200490069
[4] Suedee R., Seechammanturakit V., Suksuwan A., Canyuk B., Int. J. Mol. Sci., 2008, 9, 2333. https://doi.org/10.3390/ijms9122333
[5] Patra S., Roy E., Madhuri R., Sharma P., Anal. Chim. Acta, 2016, 918, 77. https://doi.org/10.1016/j.aca.2016.02.046
[6] Yan H., Row H., Int. J. Mol. Sci., 2006, 7, 155. https://doi.org/10.3390/i7050155
[7]JeCho S., Noh H., Won M. et al., Biosens. Bioelectron., 2018, 99, 471. https://doi.org/10.1016/j.bios.2017.08.022
[8] Hawkins D., Stevenson D., Reddy S., Anal. Chim. Acta, 2005, 542, 61. https://doi.org/10.1016/j.aca.2005.01.052
[9] Ayankojo A., Reut J., Öpik A. et al., Proceed. Estonian Acad. Sci., 2018, 67, 138. https://doi.org/10.3176/proc.2018.2.04
[10] Gálvez A., Mayorga-MatinezC., ParoloC. et al., Electrochem. Commun., 2017, 82, 6. https://doi.org/10.1016/j.elecom.2017.07.007
[11] O’Mahony J., Molinelli A., Nolan K. et al., Biosens. Bioelectron., 2005, 21, 1383. https://doi.org/10.1016/j.bios.2005.05.015
[12] VazquezM., Spivak D.:J. Polym. Sci., 2004, 42, 3668. https://doi.org/10.1002/pola.20186
[13] Takeuchi T., Haginaka J.:J. Chromatogr. B, 1999, 728, 1. https://doi.org/10.1016/S0378-4347(99)00057-2
[14] Tooth B., Pap T., Horvath V., Horvai G., Anal. Chim. Acta, 2007, 591, 17. https://doi.org/10.1016/j.aca.2007.01.016
[15] Peeters M., Troost F., Van Grinsven B., et al., Sensor. Actuat. BChem., 2012, 172, 602. https://doi.org/10.1016/j.snb.2012.05.040
[16] Turiel E., Esteban A., Anal. Chim. Acta, 2010, 668, 87. https://doi.org/10.1016/j.aca.2010.04.019
[17] Urban J., Jandera P., Schoenmakers P.:J. Chromatogr. A, 2007, 1150, 279. https://doi.org/10.1016/j.chroma.2006.09.065
[18] Wulff G., Poll H.:Macromol. Chem. Phys., 1997, 188, 741. https://doi.org/10.1002/macp.1987.021880408
[19] Okutucu B.,Telefoncu A., Talanta, 2008, 76, 1153. https://doi.org/10.1016/j.talanta.2008.05.033
[20] Chattopathyay A., Rukmini R., Mukherjee S., Biophys. J., 1996, 71, 1952. https://doi.org/10.1016/S0006-3495(96)79393-1
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[22] Bayari S., Ide S., Spectrochim. Acta A, 2003, 59, 1255. https://doi.org/10.1016/S1386-1425(02)00308-6
[23] Lagutschenkov A., LangerJ., Berden G. et al.:J. Phys. Chem. A, 2010, 114, 13268. https://doi.org/10.1021/jp109337a
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[27] Okutucu B.,Önal S., Talanta, 2011, 87, 74. https://doi.org/10.1016/j.talanta.2011.09.043
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[30] Işikver Y., Fibers and Polymers, 2017, 18, 2070. https://doi.org/10.1007/s12221-017-7215-7
[31] Saraydin D., Karadağ E., Tr. J. Chem., 1996, 20, 234.
Content type: Article
Appears in Collections:Chemistry & Chemical Technology. – 2020. – Vol. 14, No. 2



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