Please use this identifier to cite or link to this item: http://ena.lp.edu.ua:8080/handle/ntb/55772
Title: Al2(SO4)3·18H2O as an Eco-Safe Catalyst Promoting Synthesis of Polysubstituted Dihydropyrrol-2-ones
Other Titles: Al2(SO4)3·18H2O як еко-безпечний каталізатор для синтезу полізаміщених дигідропірол-2-онів
Authors: Mohamadpour, Farzaneh
Affiliation: Apadana Institute of Higher Education
Bibliographic description (Ukraine): Mohamadpour F. Al2(SO4)3·18H2O as an Eco-Safe Catalyst Promoting Synthesis of Polysubstituted Dihydropyrrol-2-ones / Farzaneh Mohamadpour // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2020. — Vol 14. — No 1. — P. 14–19.
Bibliographic description (International): Mohamadpour F. Al2(SO4)3·18H2O as an Eco-Safe Catalyst Promoting Synthesis of Polysubstituted Dihydropyrrol-2-ones / Farzaneh Mohamadpour // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2020. — Vol 14. — No 1. — P. 14–19.
Is part of: Chemistry & Chemical Technology, 1 (14), 2020
Issue: 1
Issue Date: 24-Jan-2020
Publisher: Видавництво Львівської політехніки
Lviv Politechnic Publishing House
Place of the edition/event: Львів
Lviv
DOI: doi.org/10.23939/chcht14.01.014
Keywords: багатозамещені дигідропірол-2-они
октадегідрат алюмінію сульфату
екологічно безпечний та ефективний каталізатор
одностадійний синтез
багатокомпонентна реакція
polysubstituted dihydropyrrol-2-ones
aluminum sulfate octadecahydrate
eco-safe and efficient catalyst
one-pot and facile procedure
multi-component reaction
Number of pages: 6
Page range: 14-19
Start page: 14
End page: 19
Abstract: Досліджено октадекагідрат алюмінію сульфату (Al2(SO4)3·18H2O) як ефективний та екологічно безпечний каталізатор для одностадійного чотирикомпонентного синтезу багатозаміщених дигідропірол-2-онів за реакцією діалкилацетилендикарбоксилату, формальдегіду та амінів (ароматичних та аліфатичних) за температури навколишнього середовища. Встановлено, що в присутності такого каталізатора виходи продуктів є високими, а час реакції малий. Показано, що найбільшими перевагами такого синтезу є ефективність, екологічність, недорога вартість та нетоксичність каталізатора, простота експлуатації, чіткий перебіг реакції та легкість виділення продукту без необхідності хроматографічного очищення. Визначено температури топлення продуктів та проведено 1H ЯМР-спектроскопічні дослідження.
Aluminum sulfate octadecahydrate (Al2(SO4)3·18H2O) as an efficient, mild and eco-safe catalyst for one-pot four-component synthesis of polysubstituted dihydropyrrol-2-ones from reaction between dialkyl acetylenedicarboxylate, formaldehyde and amines (aromatic and aliphatic) under ambient temperature with good to high yields and short reaction times is reported. The most benefits of this synthetic method are efficiency, environmentally benign nature, inexpensive and non-toxic catalyst, operational simplicity, clean reaction profile and ease of product isolation with no necessity of chromatographic purification steps. Products have been characterized by melting points and 1H NMR spectroscopy.
URI: http://ena.lp.edu.ua:8080/handle/ntb/55772
Copyright owner: © Національний університет “Львівська політехніка”, 2020
© Mohamadpour F., 2020
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Content type: Article
Appears in Collections:Chemistry & Chemical Technology. – 2020. – Vol. 14, No. 1



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