Please use this identifier to cite or link to this item: http://ena.lp.edu.ua:8080/handle/ntb/45156
Title: Decomposition of tert-butyl hydroperoxide in the presence of selected initiators and catalysts
Other Titles: Розклад трет-бутилгідропероксиду у присутності вибраних ініціаторів та каталізаторів
Authors: Makota, Oksana
Trach, Yuriy
Saldan, Ivan
Evers, Eike
Kalevaru, Narayana
Martin, Andreas
Affiliation: Lviv Polytechnic National University
Ivan Franko National University of Lviv
Leibniz Institute for Catalysis at the University Rostock
Bibliographic description (Ukraine): Decomposition of tert-butyl hydroperoxide in the presence of selected initiators and catalysts / Oksana Makota, Yuriy Trach, Ivan Saldan, Eike Evers, Narayana Kalevaru, Andreas Martin // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2018. — Vol 12. — No 2. — P. 154–157.
Bibliographic description (International): Decomposition of tert-butyl hydroperoxide in the presence of selected initiators and catalysts / Oksana Makota, Yuriy Trach, Ivan Saldan, Eike Evers, Narayana Kalevaru, Andreas Martin // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2018. — Vol 12. — No 2. — P. 154–157.
Is part of: Chemistry & Chemical Technology, 2 (12), 2018
Journal/Collection: Chemistry & Chemical Technology
Issue: 2
Volume: 12
Issue Date: 20-Jan-2018
Publisher: Lviv Politechnic Publishing House
Place of the edition/event: Lviv
Keywords: гідропероксид
реакція розкладу
гетерогенний каталіз
hydroperoxide
decomposition reaction
heterogeneous catalysis
Number of pages: 4
Page range: 154-157
Start page: 154
End page: 157
Abstract: Вивчено розклад трет-бутилового гідро- пероксиду в присутності ініціаторів (трет-бутилпероксид(tBuOOtBu), азодіізобутиронитрил (AIBN)) та каталізаторів(Mo2B5, MoB, Mo2B, MoSi2, VB2, VSi2). Показано, що введення радикалів може зменшити каталітичну активність. Запропоновано механізм початкової стадії розкладу трет- бутилового гідропероксиду та рівняння швидкості реакції.
Tert-butyl hydroperoxide decomposition in the presence of initiators (tert-butyl peroxide (tBuOOtBu), azodiisobutyronitrile(AIBN)) and catalysts (Mo2B5, MoB,Mo2B, MoSi2, VB2, VSi2) was studied. Our experiments suggest that the introduction of radicals may reduce the catalytic activity. The mechanism of the initial stage of tert-butyl hydroperoxide decomposition and reaction rate equation are proposed.
URI: http://ena.lp.edu.ua:8080/handle/ntb/45156
Copyright owner: © Національний університет „Львівська політехніка“, 2018
© Makota O., Trach Y., Saldan I., Evers E., Kalevaru N., Martin A., 2018
URL for reference material: https://doi.org/10.1134/S0965544116020080
https://doi.org/10.1039/C4CP04322G
https://doi.org/10.1021/jp303853h
https://doi.org/10.1016/j.jcat.2016.09.032
https://doi.org/10.1016/j.fuel.2015.10.098
https://doi.org/10.1002/anie.200462544
https://doi.org/10.1021/ja01206a017
https://doi.org/10.1002/anie.196900971
https://doi.org/10.1016/S1381-1169(98)00070-3
https://doi.org/10.1039/A709266K
https://doi.org/10.1039/A606160E
References (Ukraine): [1] Weissermel K., Arpe H.-J.: Industrial Organic Chemistry.Wiley-VCH, Weinheim 2003.
[2] Denisov E., Afanas’ev I.: Oxidation and Antioxidants in Organic Chemistry and Biology. Taylor and Francis, Boca Raton, FL 2005.
[3] Denisov E., Denisova T., Pokidova T.: Handbook of Free Radical Initiators. Wiley-VCH, Weinheim 2003.
[4] Rappoport Z.: The Chemistry of Peroxides, v. 2. Wiley-VCH, Weinheim 2006.
[5] Kharlampidi Kh., Nurullina N., Batyrshin N. et al.: Petrol. Chem., 2016, 56, 171. https://doi.org/10.1134/S0965544116020080
[6] Badra J., Fethi Kh., Raj B. et al.: Phys. Chem. Chem. Phys.,2015, 17, 2421. https://doi.org/10.1039/C4CP04322G
[7] Lam K.-Y., Davidson D., Hanson R.: J. Phys. Chem., 2012, 116,5549. https://doi.org/10.1021/jp303853h
[8] Tirso L.-A., Mercedes B., Chouzier P. et al.: J. Catal., 2016, 344,334. https://doi.org/10.1016/j.jcat.2016.09.032
[9] Elwardany A., Es-sebbar A., Khaled Et. et al.: Fuel, 2016, 166,245. https://doi.org/10.1016/j.fuel.2015.10.098
[10] Blackmond D.: Angew. Chem. Int. Ed., 2005, 44, 4302.https://doi.org/10.1002/anie.200462544
[11] Chorkendorff I., Niemantsverdriet J.: Concept ofModern Catalysis and Kinetics.:Wiley–VCH, Weinheim 2003.
[12]Milas N., Surgenor D.: J. Am. Chem. Soc., 1946, 68, 205.https://doi.org/10.1021/ja01206a017
[13] Trach Yu., Makota O., NikipanchukM. et al.: Neftekhimia,2003, 43, 424.
[14] Emanuel N., Maizus Z., Skibida I.: Angew. Chem. Int. Ed.,1969, 8, 97. https://doi.org/10.1002/anie.196900971
[15] Rothenberg G., Wiener H., Sasson Y.: J. Mol. Catal. A: Chem.,1998, 136, 253. https://doi.org/10.1016/S1381-1169(98)00070-3
[16] Barton D., Le Gloahec V., Patin H. et al.: New J. Chem., 1998,22, 559. https://doi.org/10.1039/A709266K
[17]MacFaul P., Arends I., Ingold K. et al.: J. Chem. Soc., Perkin Trans., 1997, 2, 135. https://doi.org/10.1039/A606160E
References (International): [1] Weissermel K., Arpe H.-J., Industrial Organic Chemistry.Wiley-VCH, Weinheim 2003.
[2] Denisov E., Afanas’ev I., Oxidation and Antioxidants in Organic Chemistry and Biology. Taylor and Francis, Boca Raton, FL 2005.
[3] Denisov E., Denisova T., Pokidova T., Handbook of Free Radical Initiators. Wiley-VCH, Weinheim 2003.
[4] Rappoport Z., The Chemistry of Peroxides, v. 2. Wiley-VCH, Weinheim 2006.
[5] Kharlampidi Kh., Nurullina N., Batyrshin N. et al., Petrol. Chem., 2016, 56, 171. https://doi.org/10.1134/S0965544116020080
[6] Badra J., Fethi Kh., Raj B. et al., Phys. Chem. Chem. Phys.,2015, 17, 2421. https://doi.org/10.1039/P.4CP04322G
[7] Lam K.-Y., Davidson D., Hanson R., J. Phys. Chem., 2012, 116,5549. https://doi.org/10.1021/jp303853h
[8] Tirso L.-A., Mercedes B., Chouzier P. et al., J. Catal., 2016, 344,334. https://doi.org/10.1016/j.jcat.2016.09.032
[9] Elwardany A., Es-sebbar A., Khaled Et. et al., Fuel, 2016, 166,245. https://doi.org/10.1016/j.fuel.2015.10.098
[10] Blackmond D., Angew. Chem. Int. Ed., 2005, 44, 4302.https://doi.org/10.1002/anie.200462544
[11] Chorkendorff I., Niemantsverdriet J., Concept ofModern Catalysis and Kinetics.:Wiley–VCH, Weinheim 2003.
[12]Milas N., Surgenor D., J. Am. Chem. Soc., 1946, 68, 205.https://doi.org/10.1021/ja01206a017
[13] Trach Yu., Makota O., NikipanchukM. et al., Neftekhimia,2003, 43, 424.
[14] Emanuel N., Maizus Z., Skibida I., Angew. Chem. Int. Ed.,1969, 8, 97. https://doi.org/10.1002/anie.196900971
[15] Rothenberg G., Wiener H., Sasson Y., J. Mol. Catal. A: Chem.,1998, 136, 253. https://doi.org/10.1016/S1381-1169(98)00070-3
[16] Barton D., Le Gloahec V., Patin H. et al., New J. Chem., 1998,22, 559. https://doi.org/10.1039/A709266K
[17]MacFaul P., Arends I., Ingold K. et al., J. Chem. Soc., Perkin Trans., 1997, 2, 135. https://doi.org/10.1039/A606160E
Content type: Article
Appears in Collections:Chemistry & Chemical Technology. – 2018. – Vol. 12, No. 2



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