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Title: Simultaneous methyl methacrylate and methacrylic acid obtaining over zirconium-containing catalysts
Authors: Nebesna, Yuliia
Nebesnyi, Roman
Ivasiv, Volodymyr
Lapychak, Nazarii
Affiliation: Lviv Polytechnic National University
Bibliographic description (Ukraine): Simultaneous methyl methacrylate and methacrylic acid obtaining over zirconium-containing catalysts / Yuliia Nebesna, Roman Nebesnyi, Volodymyr Ivasiv, Nazarii Lapychak // Litteris et Artibus : proceedings of the 5th International youth science forum, November 26–28, 2015, Lviv, Ukraine / Lviv Polytechnic National University. – Lviv : Lviv Polytechnic Publishing House, 2015. – P. 364–365. – Bibliography: 9 titles.
Conference/Event: Litteris et Artibus
Issue Date: 2015
Publisher: Lviv Polytechnic Publishing House
Country (code): UA
Place of the edition/event: Lviv
Keywords: methyl methacrylate
methacrylic acid
aldol condensation
zirconium oxide
Number of pages: 364-365
Abstract: Methyl methacrylate and methacrylic acid are widely used monomers. The aldol condensation of methyl propionate and formaldehyde is perspective process for simultaneous obtaining of this methacrylate monomers. It was found that zirconium-containing catalysts are active in this process. The effect of zirconium content in the catalyst on methyl propionate conversion and yield of methyl methacrylate and methacrylic acid has been determined. The best catalyst for methyl propionate condensation with formaldehyde has been found.
References (International): [1] K. Nagai, "New developments in the production of methyl methacrylate", Appl. Catal. A: Gen., vol. 221 (1-2), pp. 367-377, Dec. 2001. [2] H. A. Wittcoff, et al., Industrial organic chemicals, 3rd ed. New York: J. Wiley and Son, 2013. [3] Yu. Dmytruk, et al., “Optimum conditions determination of methyl methacrylate obtaining over tungsten-containing catalyst,” Eastern-European J. of Enterprise Technologies., vol. 6, is. 6 (76), pp. 4-7, Aug. 2015. [4] Yu. V. Dmytruk, et al., “Aldolna condensatsiia metylpropionatu z formaldehidom na В2О3 – Р2О5 – WO3/SiO2 katalizatorah [Aldol condensation of methyl propionate with formaldehyde over В2О3 – Р2О5 – WO3/SiO2 catalysts],” Visnyk Natsionalnoho tehnichnoho universytetu ”Kharkivskyi politehnichnyi instytut” – National Technical University "Kharkiv Polytechnic Institute" Bulletin, vol. 39, pp. 98-102, Sep. 2015 (in Ukraininan). [5] M. Ai, "Formation of methyl methacrylate by condensation of methyl propionate with formaldehyde over silica-supported cesium hydroxide catalysts", Appl. Cat. A: Gen., vol. 288 (1-2), p. 211-215, Apr. 2005. [6] S. Ding, et. al., "Condensation of methyl propionate with formaldehyde to methyl methacrylate over Cs- Zr-Mg/SiO2 catalysts", Adv. Mat. Res., vol. 396-398, pp. 719-723, 2012. [7] Yu. V. Nebesna, et al., “Promotuvannia osnovnymy oksydamy В2О3 – Р2О5/SiO2 katalizatora protsesu sumisnoho otrymannia metylmetakrylatu ta metakrylovoi kysloty [Promoting by basic oxides of В2О3 – Р2О5/SiO2 catalyst of the process of methyl methacrylate and methacrylic acid simultaneous obtaining],” Naukovyi Visnyk NLTU Ukrainy – Scientific Bulletin of NLTU of Ukraine, vol. 25.6, pp. 211-216, Oct. 2015 (in Ukrainian). [8] B. Li, et. al., "SBA-15 Supported cesium catalyst for methyl methacrylate synthesis via condensation of methyl propionate with formaldehyde", Ind. & Eng. Chem. Res., vol. 53, pp. 1386-1384, Jan. 2014. [9] S. D. Jackson, “Catalysts for the production of unsaturated acids or esters thereof,” U.S. Patent 6 544 924, April 8, 2003.
Content type: Conference Abstract
Appears in Collections:Litteris et Artibus. – 2015 р.

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